The TESI automated ultrasonic system shown in Figure 1
has many unique characteristics, including a water management system
that fills and empties the immersion tank as needed during testing (Stubbs
et al., 2005). For this system, a wait of 24 to 48 h to allow air bubbles
to dissipate from the water is unacceptable; fill/empty cycles occur
in times as short as 30 min. Thus, as part of the system design effort,
a technique was developed to prevent the formation of air bubbles in
the water and to hasten the dissipation of any existing bubbles. This
article describes how this water management system works and describes
qualitative observations of the presence and absence of air bubbles
in water processed by the TESI ultrasonic water management subsystem.

Figure 1 - The Turbine Engine Sustainment Initiative's automated
ultrasonic testing system.
A Quick Discussion of the Science: Temperature
and Pressure
The amount of gasses dissolved in a liquid depends on
parameters such as temperature, pressure, salinity and depth (Hitchman,
1978). It is beyond the scope of this article to go through the thermodynamics
of explaining the dependency of the solubility of gasses on these parameters.
Rather, an intuitive approach will be taken to explain the dependence
of solubility on two significant parameters: temperature and pressure.
The effect of temperature on the solubility of gasses
in water is commonly observed. Cold water in a pan initially contains
no air bubbles on the bottom of the container, but as the water is heated,
bubbles begin to form (the bubbles being less soluble in the warmer
water). The solubility of gasses in water is inversely proportional
to temperature, or

As for pressure, it is noted that cookbooks advise lowering
the temperature for cooking at higher altitudes, where the atmospheric
pressure is less. It is easier, for example, to boil water in Denver,
Colorado, which is located well above sea level, than in the Mojave
Desert, which is below sea level. Therefore, the lower the pressure,
the lower the force holding the gasses in the liquid. Solubility, then,
is directly proportional to pressure:

Combining the two proportions, we have

If we wish to remove as much gas as possible from the
water in an ultrasonic testing tank, we need to lower the solubility
by either increasing the temperature or decreasing the pressure on the
water. Since the TESI system has an open testing tank and is designed
to operate with the water temperature near room temperature, lowering
the water's gas solubility by increasing the water temperature appreciably
is impractical. The alternative approach of lowering the pressure in
the water conditioning process was pursued.

Figure 2 - Formation of bubbles in unshaken jar B and shaken jar
C after: (a) 17 min; (b) 24 h; (c) 72 h; (d) nine days.
The first design of the TESI water management system contained
a 37.9 L (10 gal) vacuum tank. As tap water flowed into the vacuum tank,
the lower pressure in the tank drew gasses out of the water. A pump
then moved the water through a filter into a large storage tank. When
the TESI ultrasonic system needed to fill the test tank, a 151 L/min
(40 gal/min) pump transferred the de-gassed water from the storage tank
to the test tank. Although the vacuum tank system successfully removed
gas bubbles from the water, it added complexity to the TESI system and
increased the probability of maintenance problems. Consequently, the
investigation into techniques for de-gassing water was continued.
A Surprising Observation
A simple experiment, originally designed to "create"
air bubbles in water, showed that allowing the water to remain dormant
for an extended period was not the most efficient way to eliminate bubbles
from a container of water. For example, Figure 2a shows a 960 mL (32
oz) specimen jar (marked B) that was filled with tap water and allowed
to stand undisturbed. A second jar (C) was also filled with tap water,
but in this case the jar was closed and shaken vigorously for about
1 min, with the desired goal being to create many bubbles in the jar.
The lid was then removed and the jar was allowed to stand undisturbed.
It was expected that many bubbles would quickly appear in the shaken
jar C, but very few, if any, would be observed in the undisturbed jar
B. However, within 15 min of filling jar B, it was observed that very
minute, dust-sized bubbles appeared, whereas only a few stray bubbles
were seen in jar C. The condition of the water in these two jars is
shown in Figure 2a, taken 17 min after the jars were filled. The squares
marked on the jars allowed the observer to count the number of bubbles
in the marked areas on the wall of the jars. Figure 2b shows the jars
after 24 h. During this 24 h period, the bubbles increased in size but
showed no signs of dissipating. As shown in Figure 2c, after 72 h little
had changed since the 24 h photograph was taken. Even after nine days,
some bubbles remained (see the top half of jar B in Figure 2d). Of course,
as would be expected, the number of bubbles in the tap water varied
in repeat tries of this experiment, but the primary trend of fewer bubbles
in the shaken jar remained.
Results of several of these air bubble experiments indicated
that, rather than keeping the water still, agitating the water released
bubbles more efficiently. Apparently, the mechanical agitation of the
water that occurred when shaking the jars effectively lowers the pressure
on the water and released gasses contained in the water. This result
caused a reevaluation of the means for de-gassing the water in the TESI
system; the vacuum system was discarded and various techniques for agitating
the water were considered.
Pursuing the Unobvious
Removing air bubbles from the water in a "passive"
fashion rather than "actively" removing them with a vacuum
tank, motor driven stirrer or other device became the goal. It was suggested
that the water be agitated by filling a storage tank from above with
water from a spray nozzle. Questions arose such as "But isn't that
how water is aerated?" and "Isn't that exactly what not to
do?" As a garden hose nozzle and water are relatively inexpensive
laboratory items, the objects were purchased and experiments quickly
created.

Figure 3 - Traditional C-scan test tank being filled by hose and
nozzle.
In the laboratory, a 1.1 by 1.2 by 0.8 m (45 by 47 by
32 in.) open ultrasonic immersion tank is typically filled by putting
a garden hose without a nozzle in the bottom of the tank and turning
on the faucet. Typically, this results in air bubbles on the walls of
the tank and on the part to be tested — and at least a 24 h wait
before starting the tests. Using a newly purchased garden hose nozzle,
the tank was filled with the nozzle placed above the tank and set to
spray into the tank (Figure 3). Although the observed outcome was now
expected, it was still surprising to see that as the tank filled, the
water was bubble-free and appeared ready to use immediately for C-scan
ultrasonic tests.
This spray nozzle technique was integrated into the TESI
system. To help eliminate air bubbles and make the water clean and free
of odors, an air separator and charcoal impregnated filter were placed
in the water source line before the nozzle. Figure 4 shows the inside
of the 946 L (250 gal) storage tank with the nozzle in place. This nozzle,
shown in Figure 5, is a full-cone brass spray nozzle for a 12.7 mm (0.5
in.) pipe. The diameter of its orifices is 5.8 mm (0.228 in.) and its
spray angle is 120º. The water in the TESI system is constantly
recirculated through the air separator, filter and nozzle when the test
and calibration tanks are not being filled or emptied.

Figure 4 - Cut away view of 946 L (250 gal) storage tank with spray
nozzle used to de-gas and store water for use, on demand, in the Turbine
Engine Sustainment Initiative's automated ultrasonic system.

Figure 5 - Standard, commercially available nozzle assembly used
in the Turbine Engine Sustainment Initiative's water storage tank.
Additional Experiments
To further study this technique of de-gassing water, a
water conditioning system identical to that used in the TESI system
was built. Tests were conducted to compare the sprayed water with water
straight out of the tap and with water that had been recirculated through
the spraying system.
Using the water conditioning test system, undisturbed
tap water (the jar labeled A in Figure 6a) was compared with the water
sprayed through the sprayer one time (jar D in Figure 6a) and with water
that had been recirculated for an hour through the spray system (jar
E). The water in these jars was observed over the course of several
days. As was seen in previous experiments, very small bubbles appeared
in undisturbed jar A just a few minutes after the jar was filled with
tap water, and the bubbles remained attached to the jar wall throughout
the observation period of nine days. The water in jar D contained a
small number of bubbles immediately after filling, and the number decreased
slowly over nine days. The recirculated water (jar E) contained no bubbles
immediately after filling and remained bubble-free for nine days. The
water in all three jars is shown immediately after filling in Figure
6a and after 24 h, 72 h, and nine days (Figures 6b, 6c and 6d, respectively).
It is clearly seen that the simple spray technique does a good job of
removing air bubbles from tap water after just one pass through the
spraying system and completely removes bubbles when allowed to recirculate
and pass multiple times through the sprayer.

Figure 6 - Formation of bubbles in unshaken jar A , nozzle sprayed
jar D and sprayed and recirculated jar E after: (a) 90 min; (b) 24 h;
(c) 72 h; (d) nine days.
Conclusion
An unobvious (at least to the author) technique has been
developed for removing gasses from water used to fill ultrasonic testing
systems. This technique vigorously agitates water by passing it through
an ordinary sprayer similar to a common garden hose. The resultant sprayed
and de-gassed water provides clean, clear, bubble-free water that is
used, on demand, to fill and empty the TESI automated ultrasonic testing
system implemented at Tinker Air Force Base. This technique of producing
bubble-free water appears to eliminate the traditional need for a "hold
time" of 24 to 48 h between the filling of an ultrasonic immersion
system tank and beginning tests. As there are no moving parts and since
only a low-cost sprayer head is used, the implementation of this technique
is very robust and easy to maintain.
Acknowledgments
The author would like to acknowledge the contributions
of Ron Cook, Dave Gasper, James Sebastian and David Stubbs, of the University
of Dayton Research Institute, to this article. Photographs were taken
by Senior Technician Greg Hartman, also of the University of Dayton
Research Institute.
REFERENCES
Hitchman, M.L., Measurement
of Dissolved Oxygen, New York, Wiley, 1978.
Stubbs, D., R. Cook, D. Erdahl,
I. Fiscus, D. Gasper, J. Hoeffel, W. Hoppe, V. Kramb, S. Kulhman,
R. Martin, R. Olding, D. Petricola, N. Powar and J. Sebastian, "An
Automated Ultrasonic System for Inspection of Aircraft Turbine Engine
Components," Insight, Vol. 47, No. 3, March 2005, pp.
157-162.